Organotrifluoroborates as attractive self-assembling systems: the case of bifunctional dipotassium phenylene-1,4-bis(trifluoroborate).

نویسندگان

  • Aurelia Falcicchio
  • Sten O Nilsson Lill
  • Filippo M Perna
  • Antonio Salomone
  • Donato I Coppi
  • Corrado Cuocci
  • Dietmar Stalke
  • Vito Capriati
چکیده

The first structure of an aromatic bis(trifluoroborate) dipotassium salt, elucidated by the combination of crystallography, DFT calculations, topological and non-covalent interaction analysis, discloses a 3D network undergoing spontaneous self-assembly thanks to the massive participation of weak intra- and intermolecular interactions for which fluorine atoms proved to play a leading role.

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عنوان ژورنال:
  • Dalton transactions

دوره 44 45  شماره 

صفحات  -

تاریخ انتشار 2015